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Apollo (For Jack)

Win all Gold Trophies on Tournament mode.

Arthur

Complete All Ring Challenges.

Bonus courses

Win on a course in Single Player Tournament mode to unlock that course.

Chun Li

Complete Second Shot on all 3 difficulty levels.

Guile (For Brian)

Win all Gold Trophies on Mirror Tournament mode.

Jill

Complete Putting on all 3 difficulty settings.

Ken (For Mark)

Win 1 Friend Play match.

Miis In 1 Player Mode

To play as your Miis in 1 Player mode you must unlock every character.

Mirror Tournament

Win all the Pro Tournament courses to unlock the Mirror Tournament.

Morrigan (For Stephanie)

Win 1 World Play match.

Pearl

Complete Tee Shot on all 3 difficulty settings.

Pro Tournament

Get a "Gold" rank on all regular Tournament courses to unlock the Pro Tournament.

Rose (For Marissa)

Win all Gold Trophies on Pro Tournament mode.

Ryu

Complete Approach Shots on all 3 difficulty levels.

Sakura

Beat All of the Wii Remote's Training Missions.

Unlock Hidden Characters

To unlock the secret characters you must successfully beat that character in a character match in 1 player mode.

Zack (For Leo)

Hit every green in Near Pin Contest on all 3 courses.